Excitation Dynamics in Disubstituted Polyacetylene

Excitation Dynamics in Disubstituted Polyacetylene

We studied the excitation dynamics in films of disubstituted polyacetylene, a degenerate groundstate conjugated polymer, using psec transient and steady-state spectroscopies. The polymer is found to support charged and neutral topological soliton excitations concurrent with a strong intrinsic photoluminescence band with quantum efficiency, h . 50%. This leads to stimulated emission in thin film...

Electronic coherence dynamics in trans-polyacetylene oligomers.

Electronic coherence dynamics in trans-polyacetylene oligomers are considered by explicitly computing the time dependent molecular polarization from the coupled dynamics of electronic and vibrational degrees of freedom in a mean-field mixed quantum-classical approximation. The oligomers are described by the Su-Schrieffer-Heeger Hamiltonian and the effect of decoherence is incorporated by propag...

Parametric Excitation in Nonlinear Dynamics

Consider a one-mass system with two degrees of freedom, nonlin-early coupled, with parametric excitation in one direction. Assuming the internal resonance 1:2 and parametric resonance 1:2 we derive conditions for stability of the trivial solution by using both the harmonic balance method and the normal form method of averaging. If the trivial solution becomes unstable a stable periodic solution...

Dynamic switching of the circularly polarized luminescence of disubstituted polyacetylene by selective transmission through a thermotropic chiral nematic liquid crystal.

The circularly polarized luminescence (CPL) of chiral disubstituted liquid-crystalline polyacetylene (di-LCPA) can be dynamically switched and amplified from left- to right-handed CPL and vice versa through the selective transmission of CPL across a thermotropic chiral nematic liquid crystal (N*-LC) phase. By combining a chiral di-LCPA CPL-emitting film with an N*-LC cell and tuning the selecti...

Spin-Charge Separation in Polyacetylene